Month: December 2018

December 2018 Vol. 4

PCN – Communicating Advances In Protective Coatings Globally in Real Time

Leading Source of Industry News on Protective Coatings for Oil & Gas, Pipelines, Marine and Construction


Jotun and Kansai Paint Announce Partnership for Protective Coatings (BREAKING NEWS)
https://www.pcimag.com/articles/105527-jotun-and-kansai-paint-announce-partnership

New Protective Marine Coating Available from PPG (BREAKING NEWS)
http://www.materialsperformance.com/news/2018/12/new-protective-marine-coating-available-in-united-states-canada

Molybdate-phosphate Conversion Coatings to Protect Steel in a Simulated Concrete Pore Solution
https://www.sciencedirect.com/science/article/abs/pii/S0257897218310405

Investigating Premature Coating Failures
Failure Analysis and Dispute Resolution for Protective Coatings Projects; NATA Certified Experts; Professional approach; +20 Years Experience; Responsive; Great Service; Services: Defect Mapping, Written Repair Procedures, Investigation & Findings.
http://www.excelplas.com/coatings-testing

Eight Halls Full Of Innovations For The International Coatings Industry For The First Time (MAJOR COATINGS EXHIBITION)
https://packagingeurope.com/eight-halls-full-of-innovations/

Corrosion Protection of Epoxy Coating with pH Sensitive Microcapsules Encapsulating Cerium Nitrate (NEW ADDITIVES)
https://www.sciencedirect.com/science/article/pii/S0010938X18314537

A Brief Review of Corrosion Protective Films and Coatings Based on Graphene and Graphene Oxide (NEW ADDITIVES)
https://www.researchgate.net/publication/
325760666_A_brief_review_of_corrosion_protective_films_and_coatings_based_on_graphene_and_graphene_oxide

PPG Acquires Anti-Corrosion Coating Formula from Navy
https://www.eurekalert.org/pub_releases/2018-12/t-paa121418.php

Axalta Wins PaintSquare’s Prestige Award for General Industrial Product Selector App
https://www.nbc-2.com/story/39637349/axalta-wins-paintsquares-prestige-award-for-general-industrial-product-selector-app

Stopping Corrosion in Mine & Quarry Structures with EonCoat™  (NEW COATINGS)
https://www.pce-international.com/2018/07/07/stopping-corrosion-in-mine-quarry-structures/

New Zealand Company Pioneers Crack-Detecting Robots for Protective  Coatings
https://invertrobotics.com/

NEW Tank Inspection Robots Can Check Coatings for Cracking and Cure (NEW ROBOTS)
https://invertrobotics.com/christchurch-based-invert-robotics-climbing-robots-are-making-waves-and-investors-are-taking-notice/

Upcoming Australian Protective Coatings and Applications Technical Seminar (4th April 2019)
https://events.corrosion.com.au/events/protective-coatings-and-applications/


This newsletter is brought to you by ExcelPlas Coating Labs (http://www.excelplas.com/)

ExcelPlas Labs provides independent testing, analysis and investigation on protective coatings to prevent corrosion.

ExcelPlas has extensive analytical capabilities for testing of Protective Coatings and Insulation Consulting for major oil and gas companies.

We conduct corrosion surveys, coating sampling, coating analysis and testing to ensure coating specifications for a wide range of onshore and offshore clients in Australia and the Asia-Pacific Region.

ExcelPlas Labs offer a full range of coating testing and analytical services to Australia’s mining, oil, gas and infrastructure sectors.

Forensic analysis for undertaking various coating based failure investigations and problem solving.

ExcelPlas Undertakes Analysis & Testing of Polymer Coating Systems including:
• Epoxy Protective Coatings
• Epoxy-Phenolic Protective Coatings
• Fusion bonded epoxy (FBE)
• Dual-Layer Fusion bonded epoxy (DLFBE)
• Liquid applied epoxy (LAE)
• Abrasion resistant overcoat (ARO)
• Three-layer PE (3LPE)
• Multi-component liquid spray  (MCL)
• Heat shrink sleeves (HSS)

Testing on Coatings that ExcelPlas can Undertake includes:
• Coating identification by Infra-red Analysis (FTIR)
• Degree of Cure by Thermal Analysis (DSC)
• Coating Filler Identification by X-ray Analysis (EDS/XRD)
• Coating Microstructure by Embedding, Polishing and Optical Microscopy (OM)
• Coating Thermal Stability and Composition by Thermogravimetric Analysis (TGA)

DSC – Phase transition/volatiles / Tg / degree of cure/characterisation
TGA – Volatile compounds, inorganic mass % mix ratio
Element mapping for chlorides on paint flakes
Microscopy -Count layers and thickness of layers
-Assess porosity and voids
-Check distribution and orientation of filler particles

Condition monitoring and analysis of corrosion prevention coatings (epoxies, epoxy-phenolics)
http://www.excelplas.com/

Testing of Epoxy Coatings (LAE, FJC, FBE), heat shrink sleeves and tapes, barrier tapes and meshes.
http://www.excelplas.com/

December 2018 Vol. 3

PCN – Communicating Advances In Protective Coatings Globally in Real Time

Leading Source of Industry News on Protective Coatings for Oil &Gas, Pipelines, Marine and Construction


Special Edition on Epoxy Coatings

Shawcor Provides Linepipe and Field Joint Coatings for the Greater Enfield Development Pipelines  (Breaking News)
https://www.pipeliner.com.au/2018/12/11/shawcor-provides-coating-solution/

Hempel Launches the One-stop Coating Solution for Incredible 60 minutes Fire Protection  (Breaking News)
https://www.hempel.com/en/news/2018/hempel-launches-the-one-stop-coating-solution-for-60-minutes-fire-protection

Robert Bryant Named Chief Executive Officer Of Axalta (Breaking News)
https://www.finanzen.net/nachricht/aktien/robert-bryant-named-chief-executive-officer-of-axalta-6926134

Sherwin-Williams Publishes Guide on Protective Coatings for Steel Pipelines (Nov 25, 2018)
https://protectiveemea.sherwin-williams.com/Documents/LiteratureLibrary/Brochures/en/Pipeclad%20Pipelines.pdf

Carboline Accepts Frost & Sullivan Award for North American Anti-Corrosion Coatings New Product Innovation (Breaking News)
https://www.workboat.com/press-release/carboline-accepts-frost-sullivan-award-for-north-american-anti-corrosion-coatings-new-product-innovation/

Sherwin-Williams Showcases Rapid Cure Epoxy for Protective Coatings of Steel
https://www.paintdocs.com/docs/webPDF.jsp?SITEID=STORECAT&doctype=PDS&lang=E&prodno=B58W610

Sherwin-Williams Coatings Provide Invaluable Protection to Naval Vessels  (Breaking News)
Fast Clad® ER, an ultra-high-solids, rapid cure, single-coat epoxy that replaced the Navy’s traditional three-step coating practice to enable faster maintenance and a 24-hour return-to-service for ballast and fuel storage tanks and other vessel assets.
https://www.paint.org/article/paints-coatings-provide-invaluable-protection-naval-vessels/

New Additive Phytic Acid Plays Key Role in the Corrosion Protection of Epoxy-Coated Rusty Steel (New Technology)
https://www.emeraldinsight.com/doi/abs/10.1108/ACMM-07-2018-1973

New Nanoparticle Encapsulation of Graphene Microsheets for Enhancing Anticorrosion Performance of Epoxy Coatings  (New Technology)
https://www.sciencedirect.com/science/article/abs/pii/S0257897218312556

New Additive Confers superhydrophobicity on Epoxy Coatings  (New Technology)
https://www.sciencedirect.com/science/article/pii/S030094401830818X

New Epoxy-based Coating reinforced with silica nanoparticles for protection of Steel Gas Pipelines  (New Technology)
https://www.tandfonline.com/doi/abs/10.1080/22243682.2018.1504232

NEW Self-Protecting Epoxy Coatings with Anticorrosion Microcapsules  (New Technology)
https://pubs.acs.org/doi/abs/10.1021/acsomega.8b01950

NEW 8-hydroxyquinoline-modified Clay Incorporated in an Epoxy Coating for the Corrosion Protection of Carbon Steel  (New Technology)
https://www.sciencedirect.com/science/article/pii/S2468023018300312

AkzoNobel Patent Novel Method for Applying Protective Coatings to Submerged Steel Articles  (New Technology)
https://patents.google.com/patent/US20180305561A1/en

Evaluations of Jotun Epoxy Coatings Performance Using Electrochemical Impedance Spectroscopic Method
http://www.alkej.com/index.php/en/article/view/102/20

Problems with Incorrect Mixing Rations of Multicomponent Epoxy Coatings (Editorial)
The component materials of epoxies are designed by the coating manufacturer to react in a particular ratio (chemically known as the stoichiometric ratio) when mixed with their corresponding parts. If the materials are not properly mixed, the chemical reaction will not occur as intended. This can result in reduced coating performance or even complete failure of the coating. In some cases, there is visual evidence of the coating material not being properly catalyzed. An applied coating may sag or appear to be wet and uncured, or remain soft due to an incorrect proportion of hardener to base material.  In other circumstances, the coating material appears to be properly cured and exhibits no visual evidence of improper catalysis. However, the electrical resistivity properties of the coating may be altered that can affect performance particularly for cathodic protection (CP) systems.

Most of the common protective coatings for pipelines consist of 2 components (base + hardener) that are mixed together just prior to use.  Mixing the components in the proper ratio (e.g. 3 : 1) is critical to the performance of the coating. If the ratio is off, curing and performance problems can occur.  An incorrect ratio can occur due to one or more of the following reasons:
– the proportions of Part A and Part B are are not correctly dosed due to volumetric errors with the metering and pumping equipment
– batch-to-batch variations in density of the Part A and Part B;
– entrained air during mixing;
– viscosity mismatch due to incorrect component temperatures;

It can be very challenging for field workers in an outside production environment to take the extreme care that is necessary to carefully measure and mix kits or drums. While laboratories can do this under very controlled ambient conditions and with graduated cylinders and balances, it requires a great deal of discipline and attention to details to get it right.

When partial kits are mixed, the individual components must be thoroughly blended before extracting the material. After a portion of the coating is removed, the containers must be immediately and thoroughly sealed, otherwise volatiles in the containers can escape, effecting later mixes.  In the case of epoxies and urethane-epoxies, moisture in the air can create problems when sealing is inadequate.  Some epoxy hardeners such as AEP can react with water.

While mixing a coating may seem like a simple task, the impact that it can have on coating performance is significant. Improper mixing can lead to an incomplete chemical reaction, resulting in reduced coating performance.  By contrast, a proper mix will give a coating material the best chance to perform as intended. Every coating is designed by its manufacturer to be mixed and applied properly. Diligently following the manufacturer’s specifications for coating preparation will increase the likelihood of peak coating performance.
http://www.excelplas.com/

Testing and Analysis of Two-component Epoxy Coating Pipeline Coatings for Correct Mix Ratio (Lab Service)
Keywords: Mix Ratio Analysis of Protal 7200, Failure Analysis of Pipeline Coatings, Testing of Denso Protal 7200 , Testing of Canusa HBE95
http://www.excelplas.com/


This newsletter is brought to you by ExcelPlas Coating Labs (http://www.excelplas.com/)

ExcelPlas Labs provides independent testing, analysis and investigation on protective coatings to prevent corrosion.

ExcelPlas has extensive analytical capabilities for testing of Protective Coatings and Insulation Consulting for major oil and gas companies.

We conduct corrosion surveys, coating sampling, coating analysis and testing to ensure coating specifications for a wide range of onshore and offshore clients in Australia and the Asia-Pacific Region.

ExcelPlas Labs offer a full range of coating testing and analytical services to Australia’s mining, oil, gas and infrastructure sectors.

Forensic analysis for undertaking various coating based failure investigations and problem solving.

ExcelPlas Undertakes Analysis & Testing of Polymer Coating Systems including:
• Epoxy Protective Coatings
• Epoxy-Phenolic Protective Coatings
• Fusion bonded epoxy (FBE)
• Dual-Layer Fusion bonded epoxy (DLFBE)
• Liquid applied epoxy (LAE)
• Abrasion resistant overcoat (ARO)
• Three-layer PE (3LPE)
• Multi-component liquid spray  (MCL)
• Heat shrink sleeves (HSS)

Testing on Coatings that ExcelPlas can Undertake includes:
• Coating identification by Infra-red Analysis (FTIR)
• Degree of Cure by Thermal Analysis (DSC)
• Coating Filler Identification by X-ray Analysis (EDS/XRD)
• Coating Microstructure by Embedding, Polishing and Optical Microscopy (OM)
• Coating Thermal Stability and Composition by Thermogravimetric Analysis (TGA)

DSC – Phase transition/volatiles / Tg / degree of cure/characterisation
TGA – Volatile compounds, inorganic mass % mix ratio
Element mapping for chlorides on paint flakes
Microscopy -Count layers and thickness of layers
-Assess porosity and voids
-Check distribution and orientation of filler particles

Condition monitoring and analysis of corrosion prevention coatings (epoxies, epoxy-phenolics)
http://www.excelplas.com/

Testing of Epoxy Coatings (LAE, FJC, FBE), heat shrink sleeves and tapes, barrier tapes and meshes.
http://www.excelplas.com/